Characterization of the rheological behavior of thermotropic liquid crystal polymers related to extrusion processes

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Abstract

In this paper, a new rheological model describing the viscosity of thermotropic liquid crystal polymers is developed. The rheological behavior of thermotropic LCP was studied using a high-pressure capillary rheometer, which was equipped with a slit die. The detailed analysis of all experimental investigations showed that the flow behavior cannot be described well with existing models. The new model combines the Bird-Carreau-Yasuda model with a specific yield stress parameter. The temperature dependence of this yield stress is considered like that of the zero-shear-rate viscosity of the Bird-Carreau-Yasuda approach. The new model does not only describe the determined data better than existing models, but it can also describe the three-region flow behavior observed by other authors excellently.

Original languageEnglish
Title of host publicationProceedings of the 36th International Conference of the Polymer Processing Society, PPS 2021
EditorsAbdellah Ajji, Frej Mighri, Hani E. Naguib
PublisherAmerican Institute of Physics Inc.
Pages020004-1 - 020004-6
ISBN (Electronic)9780735445062
DOIs
Publication statusPublished - 23 May 2023
Event36th International Conference of the Polymer Processing Society, PPS 2021 - Montreal, Canada
Duration: 26 Sept 202129 Sept 2021

Publication series

NameAIP Conference Proceedings
Volume2607
ISSN (Print)0094-243X
ISSN (Electronic)1551-7616

Conference

Conference36th International Conference of the Polymer Processing Society, PPS 2021
Country/TerritoryCanada
CityMontreal
Period26.09.202129.09.2021

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